全文获取类型
收费全文 | 19294篇 |
免费 | 1406篇 |
国内免费 | 1196篇 |
专业分类
电工技术 | 1417篇 |
综合类 | 1196篇 |
化学工业 | 1799篇 |
金属工艺 | 5881篇 |
机械仪表 | 955篇 |
建筑科学 | 855篇 |
矿业工程 | 466篇 |
能源动力 | 777篇 |
轻工业 | 481篇 |
水利工程 | 285篇 |
石油天然气 | 524篇 |
武器工业 | 145篇 |
无线电 | 724篇 |
一般工业技术 | 3831篇 |
冶金工业 | 1617篇 |
原子能技术 | 213篇 |
自动化技术 | 730篇 |
出版年
2024年 | 25篇 |
2023年 | 324篇 |
2022年 | 400篇 |
2021年 | 686篇 |
2020年 | 655篇 |
2019年 | 545篇 |
2018年 | 496篇 |
2017年 | 558篇 |
2016年 | 525篇 |
2015年 | 571篇 |
2014年 | 1009篇 |
2013年 | 1264篇 |
2012年 | 1158篇 |
2011年 | 1700篇 |
2010年 | 1081篇 |
2009年 | 1179篇 |
2008年 | 1053篇 |
2007年 | 1174篇 |
2006年 | 1147篇 |
2005年 | 974篇 |
2004年 | 884篇 |
2003年 | 752篇 |
2002年 | 568篇 |
2001年 | 466篇 |
2000年 | 445篇 |
1999年 | 355篇 |
1998年 | 265篇 |
1997年 | 267篇 |
1996年 | 206篇 |
1995年 | 210篇 |
1994年 | 173篇 |
1993年 | 137篇 |
1992年 | 107篇 |
1991年 | 70篇 |
1990年 | 86篇 |
1989年 | 65篇 |
1988年 | 38篇 |
1987年 | 43篇 |
1986年 | 31篇 |
1985年 | 22篇 |
1984年 | 29篇 |
1983年 | 26篇 |
1982年 | 25篇 |
1981年 | 16篇 |
1980年 | 18篇 |
1979年 | 12篇 |
1978年 | 15篇 |
1977年 | 5篇 |
1976年 | 7篇 |
1975年 | 8篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
《International Journal of Hydrogen Energy》2022,47(91):38682-38689
A body-centered cubic equiatomic TiZrTaNbAl multi-principal element alloy (MPEA) with elemental fluctuations was investigated to further understand the relationship between the microstructure and hydrogen distribution. In this study, a composition dependence of the hydrogen distribution was observed in the TiZrTaNbAl MPEA. An inhomogeneous electron density distribution of the MPEA was revealed by advanced differential phase-contrast scanning electron microscopy (DPC-STEM) for the first time. The results showed that the electron density has a significant effect on the hydrogen distribution in TiZrTaNbAl MPEAs. This work provides new insight into the design of materials with high hydrogen storage capacity and high hydrogen embrittlement resistance. 相似文献
2.
Grain refinement is critical for fabricating high-quality Al-Si casting components in the application of automobile and aerospace industries,while the well-known Si-poisoning effect makes it difficult.Nbbased refiners offer an effective method to refine Al-Si casting alloys,but their anti Si-poisoning capability is far from being understood.In this work,the grain refining mechanism and the anti Si-poisoning effect in the Al-10 Si/Al-5 Nb-B system were systematically investigated by combining transmission electron microscope,first-principles calculations,and thermodynamic calculations.It is revealed that NbB2provides the main nucleation site in the Al-10 Si ingot inoculated by 0.1 wt.%Nb Al-5 Nb-B refiner.The exposed Nb atoms on the(0001)NbB2and(1-100)NbB2surface can be substituted by Al to form(Al,Nb)B2intermedia layers.In addition,a layer of NbAl3-like compound(NbAl3')can cover the surface of NbB2with the orientation relation of(1-100)[11-20]NbB2//(110)[110]NbAl3'.Both of the(Al,Nb)B2and NbAl3'intermedia layers contribute to enhancing the nucleation potency of NbB2particles.These discoveries provide fundamental insight to the grain refining mechanism of the Nb-B based refiners for Al-Si casting alloys and are expected to guide the future development of stronger refiners for Al-Si casting alloys. 相似文献
3.
Qi Yang Qilong Wu Yang Liu Shuiping Luo Xiaotong Wu Xixia Zhao Haiyuan Zou Baihua Long Wen Chen Yujia Liao Lanxi Li Pei Kang Shen Lele Duan Zewei Quan 《Advanced materials (Deerfield Beach, Fla.)》2020,32(36):2002822
Engineering novel Sn-based bimetallic materials could provide intriguing catalytic properties to boost the electrochemical CO2 reduction. Herein, the first synthesis of homogeneous Sn1−xBix alloy nanoparticles (x up to 0.20) with native Bi-doped amorphous SnOx shells for efficient CO2 reduction is reported. The Bi-SnOx nanoshells boost the production of formate with high Faradaic efficiencies (>90%) over a wide potential window (−0.67 to −0.92 V vs RHE) with low overpotentials, outperforming current tin oxide catalysts. The state-of-the-art Bi-SnOx nanoshells derived from Sn0.80Bi0.20 alloy nanoparticles exhibit a great partial current density of 74.6 mA cm−2 and high Faradaic efficiency of 95.8%. The detailed electrocatalytic analyses and corresponding density functional theory calculations simultaneously reveal that the incorporation of Bi atoms into Sn species facilitates formate production by suppressing the formation of H2 and CO. 相似文献
4.
压水堆核电厂启动过程中,次级中子源为堆外源量程探测器提供本底计数率,避免测量盲区,确保反应堆安全启动。但次级中子源的引入会为核电厂带来较大的经济和环境负担,同时也需承受次级中子源破损等带来的风险。为此,可使用受辐照燃料组件的自发裂变中子源进行替代,即无源启动方式。通过研究堆外源量程探测器计数率的理论计算方法,并基于运行电厂测量数据进行分析验证,为源量程探测器计数率的理论预估提供了较为完善的理论方法流程。本文结果可为无源启动源量程探测器计数率分析提供支持,同时也可用于次级中子源装载量或布置位置的优化分析等。 相似文献
5.
《Intermetallics》2015
The structural changes induced in a CoCrCuFeNi multicomponent nano-crystalline high-entropy alloy (HEA) under fast electron irradiation were investigated by in-situ transmission electron microscopy (TEM) using a high voltage electron microscope (HVEM). A fine-grained face centered cubic (fcc) single phase was obtained in the sputtered specimens. The fcc solid solution showed high phase stability against irradiation over a wide temperature range from 298 to 773 K, and remained as the main constituent phase even when the samples were irradiated up to 40 displacement per atom (dpa). Moreover, the irradiation did not seem to induce grain coarsening. This is the first report on the irradiation damage in 5-component HEA under MeV electron irradiation. 相似文献
6.
《Intermetallics》2015
Electrical resistivity, Seebeck coefficient, specific heat and thermal conductivity measurements on the Ti50−xNi50+x (x = 0.0–1.6 at.%) shape memory alloys are performed to investigate their thermal and transport properties. In this study, anomalous features are observed in both cooling and heating cycles in all measured physical properties of the slightly Ni-rich TiNi alloys (x ≤ 1.0), corresponds to the transformation between the B19′ martensite and B2 austenite phases. Besides, the transition temperature is found to decrease gradually with increasing Ni content, and the driving force for the transition is also found to diminish slowly with the addition of excess Ni, as revealed by specific heat measurements. While the signature of martensitic transformation vanishes for the Ni-rich TiNi alloys with x ≥ 1.3, the characteristics of strain glass transition start to appear. The Seebeck coefficients of these TiNi alloys were found to be positive, suggesting the hole-type carriers dominate the thermoelectric transport. From the high-temperature Seebeck coefficients, the estimated value of Fermi energy ranges from ∼1.5 eV (Ti48.4Ni51.6) to ∼2.1 eV (Ti50Ni50), indicating the metallic nature of these alloys. In addition, the thermal conductivity of the slightly Ni-rich TiNi alloys with x ≤ 1.0 shows a distinct anomalous feature at the B19′ → B2 transition, likely due to the variation in lattice thermal conductivity. 相似文献
7.
8.
《Intermetallics》2015
An equiatomic CoCrFeNiMn high-entropy alloy was synthesized by mechanical alloying (MA) and spark plasma sintering (SPS). During MA, a solid solution with refined microstructure of 10 nm which consists of a FCC phase and a BCC phase was formed. After SPS consolidation, only one FCC phase can be detected in the HEA bulks. The as-sintered bulks exhibit high compressive strength of 1987 MPa. An interesting magnetic transition associated with the structure coarsening and phase transformation was observed during SPS process. 相似文献
9.
10.
The aim of this study was to investigate the structure and corrosion resistance of amorphous, amorphous‐crystalline, and crystalline Mg67Zn29Ca4 alloy for biodegradable applications. This paper presents a preparation method and results of the structural characterization and corrosion resistance analysis of the material. Samples were prepared in the form of 3 mm diameter rods. The structure of the alloy was examined with the use of X‐ray diffractometry and scanning electron microscopy. The thermal properties of the samples were examined with differential scanning calorimetry (DSC). Results of DSC analysis were used to determine heat treatment temperatures, allowing to obtain different fractures of crystalline phase in the material. Corrosion resistance of heat‐treated samples was investigated by immersion tests and electrochemical measurements performed in the simulated body fluid. The X‐ray diffraction results confirmed that the prepared Mg67Zn29Ca4 alloy's structure is fully amorphous. After heat treatment, samples with different fractions of amorphous phase in the structure were obtained. Immersion tests of the samples showed that the structure significantly influenced corrosion resistance in examined materials. It should be pointed out, that certain amounts of crystalline phase in amorphous matrix can greatly improve the corrosion resistance of Mg67Zn29Ca4 alloy. 相似文献